Supelco

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC(C)Nc1nc(N)nc(O)n1
InChI	1S/C6H11N5O/c1-3(2)8-5-9-4(7)10-6(12)11-5/h3H,1-2H3,(H4,7,8,9,10,11,12)
InChI key	GCKLGRUZDXSATG-UHFFFAOYSA-N

Atrazine-desethyl-desisopropyl may be used as an analytical reference standard for the quantification of the analyte in environmental samples using different chromatography techniques
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Atrazine-desethyl-desisopropyl

Empirical Formula (Hill Notation):	C₃H₄ClN₅
CAS Number:	3397-62-4
Molecular Weight:	145.55
Beilstein/REAXYS Number:	124340
EC Number:	222-260-6
MDL number:	MFCD00006054
PubChem Substance ID:	329755440
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	Nc1nc(N)nc(Cl)n1
InChI	1S/C3H4ClN5/c4-1-7-2(5)9-3(6)8-1/h(H4,5,6,7,8,9)
InChI key	FVFVNNKYKYZTJU-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Atrazine-desethyl-desisopropyl-2-hydroxy

Empirical Formula (Hill Notation):	C₃H₅N₅O
CAS Number:	645-92-1
Molecular Weight:	127.10
Beilstein/REAXYS Number:	607753
EC Number:	211-455-1
MDL number:	MFCD00023186
PubChem Substance ID:	329756834
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	Nc1nc(N)nc(O)n1
InChI	1S/C3H5N5O/c4-1-6-2(5)8-3(9)7-1/h(H5,4,5,6,7,8,9)
InChI key	MASBWURJQFFLOO-UHFFFAOYSA-N

Atrazine-desisopropyl-2-hydroxy is one of the degradation products of the herbicide atrazine, which is a persistent environmental contaminant.

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Atrazine-desisopropyl-2-hydroxy

Empirical Formula (Hill Notation):	C₅H₉N₅O
CAS Number:	7313-54-4
Molecular Weight:	155.16
MDL number:	MFCD01310649
PubChem Substance ID:	329753795
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Atrazine-desisopropyl-2-hydroxy may be used as a reference standard for the determination of the analyte in environmental water samples by liquid chromatography-tandem mass spectrometry (LC-MS2) using atmospheric pressure ionization (API) interface.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCNc1nc(N)nc(O)n1
InChI	1S/C5H9N5O/c1-2-7-4-8-3(6)9-5(11)10-4/h2H2,1H3,(H4,6,7,8,9,10,11)
InChI key	XRVCXZWINJOORX-UHFFFAOYSA-N

Azaconazole has been used as an internal standard in the determination of propiconazole, a fungistatic agent in white spruce, using gas chromatography/mass spectrometry (GC/MS).

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azaconazole

Empirical Formula (Hill Notation):	C₁₂H₁₁Cl₂N₃O₂
CAS Number:	60207-31-0
Molecular Weight:	300.14
EC Number:	262-102-3
MDL number:	MFCD00865600
PubChem Substance ID:	329754779
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Azaconazole, is an agricultural fungicide, which shows activity against wood destroying fungi and sapstain fungi. It can also play the role of a disinfectant in mushroom cultivation and in the storage of fruits and vegetables.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	Clc1ccc(c(Cl)c1)C3(Cn2cncn2)OCCO3
InChI	1S/C12H11Cl2N3O2/c13-9-1-2-10(11(14)5-9)12(18-3-4-19-12)6-17-8-15-7-16-17/h1-2,5,7-8H,3-4,6H2
InChI key	AKNQMEBLVAMSNZ-UHFFFAOYSA-N

Azamethiphos is classified under the heterocyclic organothiophosphate group of compounds.

pictograms	GHS07
signalword	Warning
hcodes	H302
pcodes	P264 - P270 - P301 + P312 - P501
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azamethiphos

Empirical Formula (Hill Notation):	C₉H₁₀ClN₂O₅PS
CAS Number:	35575-96-3
Molecular Weight:	324.68
EC Number:	252-626-0
MDL number:	MFCD00867611
PubChem Substance ID:	329756653
NACRES:	NA.24

Azamethiphos may be used as an analytical reference standard for the determination of azamethiphos in:

Salmon feed samples by ultra-high performance liquid chromatography combined with traveling-wave ion mobility/quadrupole time-of-flight mass spectrometry (UHPLC-TWIMS-QTOFMS).
Surface water samples by solid-phase extraction (SPE) and LC coupled to quadrupole-Orbitrap high resolution tandem mass spectrometry (Q-Orbitrap-MS).
Fish fillet samples by QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction and LC-QTOFMS.
Human serum samples by QuEChERS combined with LC coupled to tandem mass spectrometry (MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	COP(=O)(OC)SCN1C(=O)Oc2cc(Cl)cnc12
InChI	1S/C9H10ClN2O5PS/c1-15-18(14,16-2)19-5-12-8-7(17-9(12)13)3-6(10)4-11-8/h3-4H,5H2,1-2H3
InChI key	VNKBTWQZTQIWDV-UHFFFAOYSA-N

Azimsulfuron is a sulfonylurea based pesticide.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H302 - H317 - H331 - H410
pcodes	P261 - P273 - P280 - P301 + P312 - P302 + P352 - P304 + P340 + P311
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azimsulfuron

Empirical Formula (Hill Notation):	C₁₃H₁₆N₁₀O₅S
CAS Number:	120162-55-2
Molecular Weight:	424.40
Beilstein/REAXYS Number:	8284859
MDL number:	MFCD02102190
PubChem Substance ID:	329754002
NACRES:	NA.24

Azimsulfuron may be used as an analytical reference standard for the determination of the pesticide in:

Paddy field water by direct injection using liquid chromatography-hybrid triple quadrupole-linear ion trap-mass spectrometry (LC-QqLIT-MS).
Tap and leaching water samples by solid-phase extraction (SPE), followed by LC coupled to tandem mass spectrometry (LC-MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	COc1cc(OC)nc(NC(=O)NS(=O)(=O)c2c(cnn2C)-c3nnn(C)n3)n1
InChI	1S/C13H16N10O5S/c1-22-11(7(6-14-22)10-18-21-23(2)19-10)29(25,26)20-13(24)17-12-15-8(27-3)5-9(16-12)28-4/h5-6H,1-4H3,(H2,15,16,17,20,24)
InChI key	MAHPNPYYQAIOJN-UHFFFAOYSA-N

Azinphos-ethyl is classified under the organophosphorus family of insecticides.

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azinphos-ethyl

Empirical Formula (Hill Notation):	C₁₂H₁₆N₃O₃PS₂
CAS Number:	2642-71-9
Molecular Weight:	345.38
Beilstein/REAXYS Number:	297468
EC Number:	220-147-6
MDL number:	MFCD00055539
PubChem Substance ID:	329756654
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Azinphos-ethyl may be used as a reference standard for the determination of azinphos-ethyl in:

Water samples by solid phase extraction (SPE) and ultra-high performance liquid chromatography-quadrupole time-of-flight mass spectrometry (UHPLC-QqTOF-MS).
Cereals by QuEChERS (quick, easy, cheap, effective, rugged, and safe) extraction and gas chromatography-triple quadrupole mass spectrometry (GC-QqQ MS/MS).
Fruits and vegetables and neutraceuticals derived from grape seed extracts by QuEChERS extraction and UHPLC-QqQ MS/MS with electrospray ionization (ESI) source and multiple reaction monitoring (MRM) mode of detection.
Seawater samples by SPE and LC-ESI-MS/MS.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCOP(=S)(OCC)SCN1N=Nc2ccccc2C1=O
InChI	1S/C12H16N3O3PS2/c1-3-17-19(20,18-4-2)21-9-15-12(16)10-7-5-6-8-11(10)13-14-15/h5-8H,3-4,9H2,1-2H3
InChI key	RQVGAIADHNPSME-UHFFFAOYSA-N

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H300 - H311 - H410
pcodes	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN 2811 6.1 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azinphos-ethyl 74116-50MG

Empirical Formula (Hill Notation):	C₁₂H₁₆N₃O₃PS₂
CAS Number:	2642-71-9
Molecular Weight:	345.38
Beilstein/REAXYS Number:	297468
EC Number:	220-147-6
MDL number:	MFCD00055539
NACRES:	NA.24

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.

TraceCERT is a registered trademark of Sigma-Aldrich Co. LLC

Quality Level	300
grade	certified reference material, TraceCERT^®
product line	TraceCERT^®
shelf life	limited shelf life, expiry date on the label
application(s)	gas chromatography (GC): suitable
format	neat
storage temp.	2-8°C
SMILES string	CCOP(=S)(OCC)SCN1N=Nc2ccccc2C1=O
InChI	1S/C12H16N3O3PS2/c1-3-17-19(20,18-4-2)21-9-15-12(16)10-7-5-6-8-11(10)13-14-15/h5-8H,3-4,9H2,1-2H3
InChI key	RQVGAIADHNPSME-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H300 - H311 - H410
pcodes	P264 - P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P391
RIDADR	UN 2811 6.1 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azinphos-methyl

Empirical Formula (Hill Notation):	C₁₀H₁₂N₃O₃PS₂
CAS Number:	86-50-0
Molecular Weight:	317.32
Beilstein/REAXYS Number:	280476
EC Number:	201-676-1
MDL number:	MFCD00041814
PubChem Substance ID:	329756655
NACRES:	NA.24

Other Notes

Tandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. 45333.pdf Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.

Guthion is a registered trademark of Makhteshim Chemical Works Ltd.
PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	COP(=S)(OC)SCN1N=Nc2ccccc2C1=O
InChI	1S/C10H12N3O3PS2/c1-15-17(18,16-2)19-7-13-10(14)8-5-3-4-6-9(8)11-12-13/h3-6H,7H2,1-2H3
InChI key	CJJOSEISRRTUQB-UHFFFAOYSA-N

Azinphos-methyl-(dimethyl-d6) is an isotope-labeled analog of the organophosphorus anticholinesterase insecticide azinphos-methyl, wherein dimethoxy protons are substituted by deuterium.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H300 + H330 - H311 - H317 - H410
pcodes	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P310
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN 2811 6.1 / PGI
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azinphos-methyl-(dimethyl-d6)

Empirical Formula (Hill Notation):	C₁₀D₆H₆N₃O₃PS₂
Molecular Weight:	323.36
MDL number:	MFCD03701752
PubChem Substance ID:	329769564
NACRES:	NA.24

Azinphos-methyl-(dimethyl-d6) may be used as a deuterated internal standard to determine the levels of pesticide analytes in foods, fruits and vegetable matrices by gas chromatography (GC) based techniques.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
assay	98.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
Featured Industry	Agriculture
format	neat
storage temp.	2-8°C
SMILES string	O=C1N(CSP(OC([2H])([2H])[2H])(OC([2H])([2H])[2H])=S)N=NC2=CC=CC=C21
InChI	1S/C10H12N3O3PS2/c1-15-17(18,16-2)19-7-13-10(14)8-5-3-4-6-9(8)11-12-13/h3-6H,7H2,1-2H3/i1D3,2D3
InChI key	CJJOSEISRRTUQB-WFGJKAKNSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H300 + H330 - H311 - H317 - H410
pcodes	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P310
RIDADR	UN 2811 6.1 / PGI
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Aziprotryne

Empirical Formula (Hill Notation):	C₇H₁₁N₇S
CAS Number:	4658-28-0
Molecular Weight:	225.27
EC Number:	225-101-9
MDL number:	MFCD01002080
PubChem Substance ID:	329756657

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CSc1nc(NC(C)C)nc(N=[N+]=[N-])n1
InChI	1S/C7H11N7S/c1-4(2)9-5-10-6(13-14-8)12-7(11-5)15-3/h4H,1-3H3,(H,9,10,11,12)
InChI key	AFIIBUOYKYSPKB-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azocyclotin

Empirical Formula (Hill Notation):	C₂₀H₃₅N₃Sn
CAS Number:	41083-11-8
Molecular Weight:	436.22
Beilstein/REAXYS Number:	621636
EC Number:	255-209-1
MDL number:	MFCD00055290
PubChem Substance ID:	329756658
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	C1CCC(CC1)[Sn](C2CCCCC2)(C3CCCCC3)n4cncn4
InChI	1S/3C6H11.C2H2N3.Sn/c31-2-4-6-5-3-1;1-3-2-5-4-1;/h31H,2-6H2;1-2H;/q;;;-1;+1
InChI key	ONHBDDJJTDTLIR-UHFFFAOYSA-N

Azoxystrobin belongs to strobilurin class of fungicides which is based on lead molecule strobilurin A. Its target site is mitochondrial respiration of fungi.

pictograms	GHS05,GHS06,GHS09
signalword	Danger
hcodes	H301 - H315 - H318 - H330 - H335 - H410
pcodes	P273 - P280 - P301 + P310 + P330 - P302 + P352 - P304 + P340 + P310 - P305 + P351 + P338 + P310
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN3146 - class 6.1 - PG 1 - EHS - Organotin compounds, solid, n.o.s., HI: A, I, S (not BR)
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Azoxystrobin

Empirical Formula (Hill Notation):	C₂₂H₁₇N₃O₅
CAS Number:	131860-33-8
Molecular Weight:	403.39
Colour Index Number:	23860
MDL number:	MFCD08277047
PubChem Substance ID:	329753888
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Azoxystrobin has been used as reference for determination of azoxystrobin residue from different aquatic tox mediums using HPLC.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CO\C=C(\C(=O)OC)c1ccccc1Oc2cc(Oc3ccccc3C#N)ncn2
InChI	1S/C22H17N3O5/c1-27-13-17(22(26)28-2)16-8-4-6-10-19(16)30-21-11-20(24-14-25-21)29-18-9-5-3-7-15(18)12-23/h3-11,13-14H,1-2H3/b17-13+
InChI key	WFDXOXNFNRHQEC-GHRIWEEISA-N

Baythroid is an insecticide, that can be effectively used to control sucking insect pests in cotton crops like jassids, whiteflies and also thrips, which can suck out juices from these plants and hence, damage them.

Pictograms	GHS06,GHS09
Signal Word	Danger
Hazard Statements	H331 - H410
Precautionary Statements	P261 - P271 - P273 - P304 + P340 + P311 - P391 - P403 + P233
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN2811 - class 6.1 - PG 3 - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 2
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

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Baythroid®

Empirical Formula (Hill Notation):	C₂₂H₁₈Cl₂FNO₃
CAS Number:	68359-37-5
Molecular Weight:	434.29
Beilstein/REAXYS Number:	2788149
EC Number:	269-855-7
MDL number:	MFCD00078636
PubChem Substance ID:	329754642
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Baythroid is a registered trademark of Bayer AG
PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
description	mixture of isomers
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC1(C)C(\C=C(\Cl)Cl)C1C(=O)OC(C#N)c2ccc(F)c(Oc3ccccc3)c2
InChI	1S/C22H18Cl2FNO3/c1-22(2)15(11-19(23)24)20(22)21(27)29-18(12-26)13-8-9-16(25)17(10-13)28-14-6-4-3-5-7-14/h3-11,15,18,20H,1-2H3
InChI key	QQODLKZGRKWIFG-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H300 - H331 - H410
pcodes	P261 - P264 - P270 - P273 - P301 + P310 - P304 + P340 + P311
RIDADR	UN2811 - class 6.1 - PG 2 - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Beflubutamid

Empirical Formula (Hill Notation):	C₁₈H₁₇F₄NO₂
CAS Number:	113614-08-7
Molecular Weight:	355.33
MDL number:	MFCD04112601
PubChem Substance ID:	329754369

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCC(Oc1ccc(F)c(c1)C(F)(F)F)C(=O)NCc2ccccc2
InChI	1S/C18H17F4NO2/c1-2-16(17(24)23-11-12-6-4-3-5-7-12)25-13-8-9-15(19)14(10-13)18(20,21)22/h3-10,16H,2,11H2,1H3,(H,23,24)
InChI key	FFQPZWRNXKPNPX-UHFFFAOYSA-N

Benalaxyl is a phenylamide fungicide used for the control of Oomycetes, particularly fungi of the family Peronosporaceae, Phythophthora plasmopara, and Pythium spp. Benalaxyl acts by inhibiting RNA polymerization (polymerase complex I).
Benalaxyl is a systemic fungicide belonging to the acylalanine family. It is found to be active against Oomycetes belonging to Peronosporaceae family.

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273
Personal Protective Equipment	Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3

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Benalaxyl

Empirical Formula (Hill Notation):	C₂₀H₂₃NO₃
CAS Number:	71626-11-4
Molecular Weight:	325.40
Beilstein/REAXYS Number:	3001587
EC Number:	275-728-7
MDL number:	MFCD00143652
PubChem Substance ID:	329753686
NACRES:	NA.24

Benalaxyl may be used as a reference standard for the determination of the analyte in water and wine samples using enzyme linked immunosorbent assay (ELISA).
Benalaxyl may be used as a fungicide reference standard for the determination of the analyte:

In rabbit plasma by a chiral high-performance liquid chromatography method with a diode array detector (HPLC-DAD).
In vegetable samples by gas chromatography-tandem mass spectrometry (GC-MS-MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	COC(=O)C(C)N(C(=O)Cc1ccccc1)c2c(C)cccc2C
InChI	1S/C20H23NO3/c1-14-9-8-10-15(2)19(14)21(16(3)20(23)24-4)18(22)13-17-11-6-5-7-12-17/h5-12,16H,13H2,1-4H3
InChI key	CJPQIRJHIZUAQP-UHFFFAOYSA-N

Benalaxyl-M is a phenyl-amide fungicide which is effective in controlling downy mildew of grapes. The mode of action involves inhibiting nucleic RNA polymerase enzyme.

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273 - P391 - P501
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benalaxyl-M

Empirical Formula (Hill Notation):	C₂₀H₂₃NO₃
CAS Number:	98243-83-5
Molecular Weight:	325.40
MDL number:	MFCD11616749
PubChem Substance ID:	329754380
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Benalaxyl-M may be used as a reference standard for the determination of benalaxyl-M in wine samples by solid-phase extraction (SPE) and liquid chromatography (LC) tandem mass spectrometry (MS/MS), based on a hybrid quadrupole time-of-flight (QTOF) system.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	COC(=O)[C@@H](C)N(C(=O)Cc1ccccc1)c2c(C)cccc2C
InChI	1S/C20H23NO3/c1-14-9-8-10-15(2)19(14)21(16(3)20(23)24-4)18(22)13-17-11-6-5-7-12-17/h5-12,16H,13H2,1-4H3/t16-/m1/s1
InChI key	CJPQIRJHIZUAQP-MRXNPFEDSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Personal Protective Equipment	Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benazolin-ethyl ester

Empirical Formula (Hill Notation):	C₁₁H₁₀ClNO₃S
CAS Number:	25059-80-7
Molecular Weight:	271.72
Beilstein/REAXYS Number:	753659
EC Number:	246-591-0
MDL number:	MFCD00143653
PubChem Substance ID:	329753688
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCOC(=O)CN1C(=O)Sc2cccc(Cl)c12
InChI	1S/C11H10ClNO3S/c1-2-16-9(14)6-13-10-7(12)4-3-5-8(10)17-11(13)15/h3-5H,2,6H2,1H3
InChI key	WQRCEBAZAUAUQC-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS09
hcodes	H411
pcodes	P273
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bendiocarb

Empirical Formula (Hill Notation):	C₁₁H₁₃NO₄
CAS Number:	22781-23-3
Molecular Weight:	223.23
Beilstein/REAXYS Number:	1315404
EC Number:	245-216-8
MDL number:	MFCD00078629
PubChem Substance ID:	329756659
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CNC(=O)Oc1cccc2OC(C)(C)Oc12
InChI	1S/C11H13NO4/c1-11(2)15-8-6-4-5-7(9(8)16-11)14-10(13)12-3/h4-6H,1-3H3,(H,12,13)
InChI key	XEGGRYVFLWGFHI-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H300 - H311 + H331 - H410
pcodes	P261 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN2811 - class 6.1 - PG 2 - MP - RQ - Toxic solids, organic, n.o.s. HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benfluralin

Empirical Formula (Hill Notation):	C₁₃H₁₆F₃N₃O₄
CAS Number:	1861-40-1
Molecular Weight:	335.28
Beilstein/REAXYS Number:	2821329
EC Number:	217-465-2
MDL number:	MFCD00078630
PubChem Substance ID:	329756660

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCCCN(CC)c1c(cc(cc1[N+]([O-])=O)C(F)(F)F)[N+]([O-])=O
InChI	1S/C13H16F3N3O4/c1-3-5-6-17(4-2)12-10(18(20)21)7-9(13(14,15)16)8-11(12)19(22)23/h7-8H,3-6H2,1-2H3
InChI key	SMDHCQAYESWHAE-UHFFFAOYSA-N

Benfuracarb belongs to the benzofuranyl methylcarbamate insecticide group of pesticides used to control insect pests in citrus, maize, sugar beet and vegetables.

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273
Personal Protective Equipment	Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benfuracarb

Empirical Formula (Hill Notation):	C₂₀H₃₀N₂O₅S
CAS Number:	82560-54-1
Molecular Weight:	410.53
MDL number:	MFCD00210247
PubChem Substance ID:	329753802

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Benfuracarb may be used as a reference standard for the determination of the analyte:

In bananas by application of a modified QuEChERS procedure followed by ultra high performance liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS/MS).
In honeybees, honey and bee pollen by liquid chromatography coupled to tandem mass spectrometry.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
format	neat
SMILES string	CCOC(=O)CCN(SN(C)C(=O)Oc1cccc2CC(C)(C)Oc12)C(C)C
InChI	1S/C20H30N2O5S/c1-7-25-17(23)11-12-22(14(2)3)28-21(6)19(24)26-16-10-8-9-15-13-20(4,5)27-18(15)16/h8-10,14H,7,11-13H2,1-6H3
InChI key	FYZBOYWSHKHDMT-UHFFFAOYSA-N

Benfuresate is a herbicide which is specifically effective against Digitaria, Sectaria, Cyperus, Portulaca, Solanum and Gallium weeds. Benfuresate mode of action involves inhibiting fat synthesis.

pictograms	GHS06,GHS08,GHS09
signalword	Danger
hcodes	H302 - H331 - H361f - H410
pcodes	P201 - P273 - P301 + P312 + P330 - P304 + P340 + P311 - P308 + P313
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	212.0 °F
Flash Point C	> 100 °C

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Benfuresate

Empirical Formula (Hill Notation):	C₁₂H₁₆O₄S
CAS Number:	68505-69-1
Molecular Weight:	256.32
EC Number:	270-925-4
MDL number:	MFCD01728672
PubChem Substance ID:	329753857
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Benfuresate may be used as a reference standard in the determination of the analyte in water and urine samples by an analytical method based on coupling photo-induced chemiluminescence in a multicommutation continuous flow methodology.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCS(=O)(=O)Oc1ccc2OCC(C)(C)c2c1
InChI	1S/C12H16O4S/c1-4-17(13,14)16-9-5-6-11-10(7-9)12(2,3)8-15-11/h5-7H,4,8H2,1-3H3
InChI key	QGQSRQPXXMTJCM-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benodanil

Empirical Formula (Hill Notation):	C₁₃H₁₀INO
CAS Number:	15310-01-7
Molecular Weight:	323.13
Beilstein/REAXYS Number:	2725018
EC Number:	239-352-7
MDL number:	MFCD00078638
PubChem Substance ID:	329756661
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	Ic1ccccc1C(=O)Nc2ccccc2
InChI	1S/C13H10INO/c14-12-9-5-4-8-11(12)13(16)15-10-6-2-1-3-7-10/h1-9H,(H,15,16)
InChI key	LJOZMWRYMKECFF-UHFFFAOYSA-N

Benoxacor is a dichloroacetamide herbicide safener, used to protect corn against injury from metolachlor. Its role as a safener involves inducing the enzymatic mechanism of chloroacetanilide detoxification in plants.

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benoxacor

Empirical Formula (Hill Notation):	C₁₁H₁₁Cl₂NO₂
CAS Number:	98730-04-2
Molecular Weight:	260.12
Beilstein/REAXYS Number:	4190275
MDL number:	MFCD01311820
PubChem Substance ID:	329757047
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Benoxacor may be used as a reference standard in the determination of benoxacor in wheat and soil samples using gas chromatography (GC) and high performance liquid chromatography (HPLC).

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC1COc2ccccc2N1C(=O)C(Cl)Cl
InChI	1S/C11H11Cl2NO2/c1-7-6-16-9-5-3-2-4-8(9)14(7)11(15)10(12)13/h2-5,7,10H,6H2,1H3
InChI key	PFJJMJDEVDLPNE-UHFFFAOYSA-N

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H317 - H410
pcodes	P261 - P272 - P273 - P280 - P302 + P352 - P333 + P313
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benoxacor 6688-25MG

Empirical Formula (Hill Notation):	C₁₁H₁₁Cl₂NO₂
CAS Number:	98730-04-2
Molecular Weight:	260.12
Beilstein/REAXYS Number:	4190275
MDL number:	MFCD01311820

This reference material (RM) is produced and certified in accordance with ISO/IEC 17025. This RM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content incl. uncertainty and expiry date are given on the certificate.

grade	reference material
assay	≥97.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
format	neat
SMILES string	CC1COc2ccccc2N1C(=O)C(Cl)Cl
InChI	1S/C11H11Cl2NO2/c1-7-6-16-9-5-3-2-4-8(9)14(7)11(15)10(12)13/h2-5,7,10H,6H2,1H3
InChI key	PFJJMJDEVDLPNE-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H317 - H410
pcodes	P261 - P272 - P273 - P280 - P302 + P352 - P333 + P313
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bensulfuron-methyl

Empirical Formula (Hill Notation):	C₁₆H₁₈N₄O₇S
CAS Number:	83055-99-6
Molecular Weight:	410.40
Beilstein/REAXYS Number:	7447488
EC Number:	401-340-6
MDL number:	MFCD00128064
PubChem Substance ID:	329755713
NACRES:	NA.24

Caution

Sensitive, handle under argon.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, NMR: suitable, gas chromatography (GC): suitable
impurities	1% water (Karl Fischer)
mp	179-184 °C
suitability	passes test for identity (NMR)
Featured Industry	Agriculture Environmental
format	neat
SMILES string	COC(=O)c1ccccc1CS(=O)(=O)NC(=O)Nc2nc(OC)cc(OC)n2
InChI	1S/C16H18N4O7S/c1-25-12-8-13(26-2)18-15(17-12)19-16(22)20-28(23,24)9-10-6-4-5-7-11(10)14(21)27-3/h4-8H,9H2,1-3H3,(H2,17,18,19,20,22)
InChI key	XMQFTWRPUQYINF-UHFFFAOYSA-N

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H317 - H411
pcodes	P261 - P272 - P273 - P280 - P302 + P352 - P333 + P313
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bensulfuron-methyl 6698-50MG

Empirical Formula (Hill Notation):	C₁₆H₁₈N₄O₇S
CAS Number:	83055-99-6
Molecular Weight:	410.40
Beilstein/REAXYS Number:	7447488
MDL number:	MFCD00128064

Quality Level	200
grade	reference material
assay	≥97.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
format	neat
SMILES string	COC(=O)c1ccccc1CS(=O)(=O)NC(=O)Nc2nc(OC)cc(OC)n2
InChI	1S/C16H18N4O7S/c1-25-12-8-13(26-2)18-15(17-12)19-16(22)20-28(23,24)9-10-6-4-5-7-11(10)14(21)27-3/h4-8H,9H2,1-3H3,(H2,17,18,19,20,22)
InChI key	XMQFTWRPUQYINF-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H317 - H411
pcodes	P261 - P272 - P273 - P280 - P302 + P352 - P333 + P313
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bensulide

Empirical Formula (Hill Notation):	C₁₄H₂₄NO₄PS₃
CAS Number:	741-58-2
Molecular Weight:	397.51
Beilstein/REAXYS Number:	2164989
EC Number:	212-010-4
MDL number:	MFCD00055362
PubChem Substance ID:	329753779

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC(C)OP(=S)(OC(C)C)SCCNS(=O)(=O)c1ccccc1
InChI	1S/C14H24NO4PS3/c1-12(2)18-20(21,19-13(3)4)22-11-10-15-23(16,17)14-8-6-5-7-9-14/h5-9,12-13,15H,10-11H2,1-4H3
InChI key	RRNIZKPFKNDSRS-UHFFFAOYSA-N

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H410
pcodes	P273 - P301 + P312 + P330
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bensulide 6702-50MG

Empirical Formula (Hill Notation):	C₁₄H₂₄NO₄PS₃
CAS Number:	741-58-2
Molecular Weight:	397.51
Beilstein/REAXYS Number:	2164989
MDL number:	MFCD00055362

This reference material (RM) is produced and certified in accordance with ISO/IEC 17025. This RM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content incl. uncertainty and expiry date are given on the certificate.

Bensultap is a broad spectrum, carbamate insecticide used for the control of pests such as leaf rollers, beetles, leaf miners, borers, boll, root weevils, and various moths in crop and fruit plantations. Its mode of action involves the blocking of synaptic neuron transmissions in the central nervous system (CNS) of insect pests.
Bensultap is a broad spectrum, carbamate insecticide used for the control of pests such as leaf rollers, beetles, leaf miners, borers, boll, root weevils and various moths in crop and fruit plantations. Its mode of action involves the blocking of synaptic neuron transmissions in the central nervous system (CNS) of insect pests.

Quality Level	200
grade	reference material
assay	≥97.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
format	neat
storage temp.	2-8°C
SMILES string	CC(C)OP(=S)(OC(C)C)SCCNS(=O)(=O)c1ccccc1
InChI	1S/C14H24NO4PS3/c1-12(2)18-20(21,19-13(3)4)22-11-10-15-23(16,17)14-8-6-5-7-9-14/h5-9,12-13,15H,10-11H2,1-4H3
InChI key	RRNIZKPFKNDSRS-UHFFFAOYSA-N

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Bensultap

Empirical Formula (Hill Notation):	C₁₇H₂₁NO₄S₄
CAS Number:	17606-31-4
Molecular Weight:	431.61
MDL number:	MFCD00210246
PubChem Substance ID:	329754676

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Bensultap may be used as an analytical reference standard for the determination of the analyte in crop and soil samples using high performance liquid chromatography and gas chromatography with flame photometric detection.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CN(C)C(CSS(=O)(=O)c1ccccc1)CSS(=O)(=O)c2ccccc2
InChI	1S/C17H21NO4S4/c1-18(2)15(13-23-25(19,20)16-9-5-3-6-10-16)14-24-26(21,22)17-11-7-4-8-12-17/h3-12,15H,13-14H2,1-2H3
InChI key	YFXPPSKYMBTNAV-UHFFFAOYSA-N

Bentazon is a commonly used pesticide which effectively controls weed in paddy fields.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H410
pcodes	P273 - P301 + P312 + P330
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bentazon

Empirical Formula (Hill Notation):	C₁₀H₁₂N₂O₃S
CAS Number:	25057-89-0
Molecular Weight:	240.28
Beilstein/REAXYS Number:	530220
EC Number:	246-585-8
MDL number:	MFCD00078640
PubChem Substance ID:	329753982
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Bentazon has been used as analytical standard in liquid chromatograph with a photodiode array (PDA) detector coupled in series with a mass spectroscopy (MS) detector equipped with an atmospheric pressure electrospray ionization source (ESI) for the determination of bentazon and its transformation products.

Other Notes

Tandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. 32052.pdf Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC(C)N1C(=O)c2ccccc2NS1(=O)=O
InChI	1S/C10H12N2O3S/c1-7(2)12-10(13)8-5-3-4-6-9(8)11-16(12,14)15/h3-7,11H,1-2H3
InChI key	ZOMSMJKLGFBRBS-UHFFFAOYSA-N

Bentazon-d7 is a deuterated form of bentazon, typically used for environmental and food residue analysis.

pictograms	GHS07
signalword	Warning
hcodes	H302 - H317 - H319 - H412
pcodes	P261 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bentazon-d7

Empirical Formula (Hill Notation):	C₁₀D₇H₅N₂O₃S
CAS Number:	131842-77-8
Molecular Weight:	247.32
MDL number:	MFCD09953755
PubChem Substance ID:	329754412
NACRES:	NA.24

Bentazon-d7 may be used as an internal standard for the determination of bentazon in shellfish by ultra-high performance liquid chromatography-high resolution mass spectrometry (UHPLC-HRMS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
mass shift	M+7
SMILES string	[2H]C([2H])([2H])C([2H])(N1C(=O)c2ccccc2NS1(=O)=O)C([2H])([2H])[2H]
InChI	1S/C10H12N2O3S/c1-7(2)12-10(13)8-5-3-4-6-9(8)11-16(12,14)15/h3-7,11H,1-2H3/i1D3,2D3,7D
InChI key	ZOMSMJKLGFBRBS-QXMYYZBZSA-N

Benthiavalicarb isopropyl is classified under the class of amino acid amide carbamate category of fungicides.

pictograms	GHS07
signalword	Warning
hcodes	H302 - H317 - H319 - H412
pcodes	P261 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
Personal Protective Equipment	Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benthiavalicarb isopropyl

Empirical Formula (Hill Notation):	C₁₈H₂₄FN₃O₃S
CAS Number:	177406-68-7
Molecular Weight:	381.46
MDL number:	MFCD08690472
PubChem Substance ID:	329754435
NACRES:	NA.24

Benthiavalicarb isopropyl may be used as an analytical reference standard for the determination of benthiavalicarb isopropyl in:

Fruits and vegitables by ultra-performance liquid chromatography coupled to quadrupole-time-of-flight-mass spectrometry (UPLC-QTOF-MS) equipped with automated detection.
Food samples and human serum samples by QuEChERS (quick, easy, cheap, effective, rigged, and safe) extraction LC coupled to electrospray ionization-tandem mass spectrometry (ESI-MS/MS) equipped with multiple reaction monitoring (MRM) detection.
Chinese cabbage and cucumber samples by QuEChERS extraction, primary secondary amine dispersive solid-phase extraction (PSA d-SPE) and LC-ESI-MS/MS with selected reaction monitoring (SRM) detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	20°C
SMILES string	CC(C)OC(=O)N[C@@H](C(C)C)C(=O)N[C@H](C)c1nc2ccc(F)cc2s1
InChI	1S/C18H24FN3O3S/c1-9(2)15(22-18(24)25-10(3)4)16(23)20-11(5)17-21-13-7-6-12(19)8-14(13)26-17/h6-11,15H,1-5H3,(H,20,23)(H,22,24)/t11-,15?/m1/s1
InChI key	USRKFGIXLGKMKU-ZRKZCGFPSA-N

Bentranil is a herbicide, which is used for the postemergence control of annual weeds in cereal crops, rice and maize.

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bentranil

Empirical Formula (Hill Notation):	C₁₄H₉NO₂
CAS Number:	1022-46-4
Molecular Weight:	223.23
Beilstein/REAXYS Number:	170624
MDL number:	MFCD00043598
PubChem Substance ID:	329755700

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Bentranil may be used as an analytical reference standard for the quantification of the analyte in roots of Murdannia lanuginosa and Murdannia simplex using gas chromatography coupled to mass spectrometry.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
bp	189-192 °C/8 mmHg (lit.)
mp	123-125 °C (lit.)
Featured Industry	Agriculture Environmental
format	neat
SMILES string	O=C1OC(=Nc2ccccc12)c3ccccc3
InChI	1S/C14H9NO2/c16-14-11-8-4-5-9-12(11)15-13(17-14)10-6-2-1-3-7-10/h1-9H
InChI key	HTTLBYITFHMYFK-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Benzoylprop-ethyl may be used as a reference standard for the determination of the analyte:

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benzoylprop-ethyl

Empirical Formula (Hill Notation):	C₁₈H₁₇Cl₂NO₃
CAS Number:	22212-55-1
Molecular Weight:	366.24
Beilstein/REAXYS Number:	2899940
EC Number:	244-845-5
MDL number:	MFCD00143676
PubChem Substance ID:	329753780
NACRES:	NA.24

In various fruits and vegetables by gas chromatography/mass spectrometry (GC/MS) and liquid chromatography with fluorescence detection (LC-FLD).
In animal tissues by gel permeation chromatography (GPC) cleanup followed by GC–MS and liquid chromatography-tandem mass spectrometry (LC–MS–MS).

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100,
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCOC(=O)C(C)N(C(=O)c1ccccc1)c2ccc(Cl)c(Cl)c2
InChI	1S/C18H17Cl2NO3/c1-3-24-18(23)12(2)21(14-9-10-15(19)16(20)11-14)17(22)13-7-5-4-6-8-13/h4-12H,3H2,1-2H3
InChI key	SLCGUGMPSUYJAY-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H410
pcodes	P273 - P301 + P312 + P330
Personal Protective Equipment	dust mask type N95 (US),, Eyeshields,, Gloves,
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Benzthiazuron

Empirical Formula (Hill Notation):	C₉H₉N₃OS
CAS Number:	1929-88-0
Molecular Weight:	207.25
Beilstein/REAXYS Number:	181259
EC Number:	217-685-9
MDL number:	MFCD00055363
PubChem Substance ID:	329755396
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CNC(=O)Nc1nc2ccccc2s1
InChI	1S/C9H9N3OS/c1-10-8(13)12-9-11-6-4-2-3-5-7(6)14-9/h2-5H,1H3,(H2,10,11,12,13)
InChI key	DTCJYIIKPVRVDD-UHFFFAOYSA-N

Bifenazate is a selective carbazate acaricide primarily used for the control of phytophagous mites infesting agricultural and ornamental crops.

pictograms	GHS07
signalword	Warning
hcodes	H302
pcodes	P301 + P312 + P330
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 1
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bifenazate

Empirical Formula (Hill Notation):	C₁₇H₂₀N₂O₃
CAS Number:	149877-41-8
Molecular Weight:	300.35
Beilstein/REAXYS Number:	9632665
EC Number:	442-820-5
MDL number:	MFCD03792817
PubChem Substance ID:	329754253
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Bifenazate may be used as a reference standard for the determination of bifenazate from edible oils (olive, soya and sunflower) by liquid chromatography-tandem mass spectrometry employing new generation materials for dispersive solid phase extraction clean-up.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	COc1ccc(cc1NNC(=O)OC(C)C)-c2ccccc2
InChI	1S/C17H20N2O3/c1-12(2)22-17(20)19-18-15-11-14(9-10-16(15)21-3)13-7-5-4-6-8-13/h4-12,18H,1-3H3,(H,19,20)
InChI key	VHLKTXFWDRXILV-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07,GHS08,GHS09
signalword	Warning
hcodes	H317 - H373 - H410
pcodes	P260 - P272 - P273 - P280 - P302 + P352 - P314
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3

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Bifenox

Empirical Formula (Hill Notation):	C₁₄H₉Cl₂NO₅
CAS Number:	42576-02-3
Molecular Weight:	342.13
Beilstein/REAXYS Number:	2170169
EC Number:	255-894-7
MDL number:	MFCD00055314
PubChem Substance ID:	329753781
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	COC(=O)c1cc(Oc2ccc(Cl)cc2Cl)ccc1[N+]([O-])=O
InChI	1S/C14H9Cl2NO5/c1-21-14(18)10-7-9(3-4-12(10)17(19)20)22-13-5-2-8(15)6-11(13)16/h2-7H,1H3
InChI key	SUSRORUBZHMPCO-UHFFFAOYSA-N

Bifenthrin (BF) is a pyrethroid insecticide widely used in urban and agricultural applications.

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273 - P501
Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bifenthrin

Empirical Formula (Hill Notation):	C₂₃H₂₂ClF₃O₂
CAS Number:	99267-18-2
Molecular Weight:	422.87
PubChem Substance ID:	329754939
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Bifenthrin may be used as an analytical reference standard for the determination of the analyte in vegetables, ground and sea water and tea samples by various chromatography techniques.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC1(C)C(C(OCC2=C(C)C(C3=CC=CC=C3)=CC=C2)=O)C1/C=C(Cl)/C(F)(F)F

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Bifenthrin solution has been used as internal standard in the determination of pesticides in tomatoes by solid–liquid extraction, followed by purification and separation at low temperature, using gas chromatography coupled with mass spectrometry (GC-MS).

pictograms	GHS06,GHS08,GHS09
signalword	Danger
hcodes	H300 - H317 - H331 - H351 - H372 - H410
pcodes	P201 - P273 - P280 - P301 + P310 - P302 + P352 - P304 + P340 + P311
Target Organs	Nervous system
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	UN2811 - class 6.1 - PG 2 - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bifenthrin solution

Empirical Formula (Hill Notation):	C₂₃H₂₂ClF₃O₂
CAS Number:	99267-18-2
Molecular Weight:	422.87
MDL number:	MFCD00143694
PubChem Substance ID:	329755566
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
shelf life	limited shelf life, expiry date on the label
concentration	100 µg/mL in acetonitrile
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	single component solution
storage temp.	2-8°C
SMILES string	Cc1c(COC(=O)[C@H]2[C@@H](\C=C(/Cl)C(F)(F)F)C2(C)C)cccc1-c3ccccc3
InChI	1S/C23H22ClF3O2/c1-14-16(10-7-11-17(14)15-8-5-4-6-9-15)13-29-21(28)20-18(22(20,2)3)12-19(24)23(25,26)27/h4-12,18,20H,13H2,1-3H3/b19-12-/t18-,20-/m1/s1
InChI key	OMFRMAHOUUJSGP-JHEGMOCKSA-N

pictograms	GHS02,GHS07,GHS09
signalword	Danger
hcodes	H225 - H302 + H312 + H332 - H319 - H410
pcodes	P210 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN 1648 3 / PGII
WGK Germany	WGK 3
Flash Point F	46.4 °F
Flash Point C	8 °C

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Binapacryl

Empirical Formula (Hill Notation):	C₁₅H₁₈N₂O₆
CAS Number:	485-31-4
Molecular Weight:	322.31
Beilstein/REAXYS Number:	2013712
MDL number:	MFCD00055425

Quality Level	200
grade	reference material
assay	≥98.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
format	neat
storage temp.	2-8°C
SMILES string	CCC(C)c1cc(cc(c1OC(=O)\C=C(/C)C)[N+]([O-])=O)[N+]([O-])=O
InChI	1S/C15H18N2O6/c1-5-10(4)12-7-11(16(19)20)8-13(17(21)22)15(12)23-14(18)6-9(2)3/h6-8,10H,5H2,1-4H3
InChI key	ZRDUSMYWDRPZRM-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS08,GHS09
signalword	Danger
hcodes	H301 + H311 - H360D - H410
pcodes	P201 - P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312
WGK Germany	WGK 3

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Bioallethrin

Empirical Formula (Hill Notation):	C₁₉H₂₆O₃
CAS Number:	584-79-2
Molecular Weight:	302.41
Beilstein/REAXYS Number:	2294836
EC Number:	209-542-4
MDL number:	MFCD00045443
PubChem Substance ID:	329753786
NACRES:	NA.24

Caution

Light sensitive.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
storage condition	under inert gas (argon)
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	C\C(C)=C\C1C(C(=O)OC2CC(=O)C(CC=C)=C2C)C1(C)C
InChI	1S/C19H26O3/c1-7-8-13-12(4)16(10-15(13)20)22-18(21)17-14(9-11(2)3)19(17,5)6/h7,9,14,16-17H,1,8,10H2,2-6H3
InChI key	ZCVAOQKBXKSDMS-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Biphenyl may also serve as a polymerizable electrolyte additive for overcharge protection of lithium ion batteries.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 + H332 - H410
pcodes	P273 - P301 + P312 + P330 - P304 + P340 + P312
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Biphenyl

Empirical Formula (Hill Notation):	C₁₂H₁₀
Linear Formula:	C₆H₅C₆H₅
CAS Number:	92-52-4
Molecular Weight:	154.21
Beilstein/REAXYS Number:	1634058
EC Number:	202-163-5
MDL number:	MFCD00003054
PubChem Substance ID:	329755216
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
vapor density	5.31 (vs air)
vapor pressure	9.46 mmHg ( 115 °C)
product line	PESTANAL^®
form	neat
autoignition temp.	1004 °F
shelf life	limited shelf life, expiry date on the label
expl. lim.	0.6 %, 111 °F, 5.8 %, 166 °F
application(s)	HPLC: suitable, gas chromatography (GC): suitable
bp	255 °C (lit.)
mp	68-70 °C (lit.)
Featured Industry	Agriculture Environmental
format	neat
SMILES string	c1ccc(cc1)-c2ccccc2
InChI	1S/C12H10/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H
InChI key	ZUOUZKKEUPVFJK-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H315 - H319 - H335 - H410
pcodes	P273 - P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	230.0 °F - closed cup
Flash Point C	110 °C - closed cup

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Bis(2-ethylhexyl) phthalate

Empirical Formula (Hill Notation):	C₂₄H₃₈O₄
CAS Number:	117-81-7
Molecular Weight:	390.56
Beilstein/REAXYS Number:	1890696
EC Number:	204-211-0
MDL number:	MFCD00009493
PubChem Substance ID:	329755483
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
bp	386 °C (lit.)
density	0.985 g/mL at 20 °C (lit.)
Featured Industry	Agriculture Cleaning Products Cosmetics Environmental Food and Beverages Personal Care
format	neat
SMILES string	CCCCC(CC)COC(=O)c1ccccc1C(=O)OCC(CC)CCCC
InChI	1S/C24H38O4/c1-5-9-13-19(7-3)17-27-23(25)21-15-11-12-16-22(21)24(26)28-18-20(8-4)14-10-6-2/h11-12,15-16,19-20H,5-10,13-14,17-18H2,1-4H3
InChI key	BJQHLKABXJIVAM-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Pictograms	GHS08
Signal Word	Danger
Hazard Statements	H360FD
Precautionary Statements	P201 - P202 - P280 - P308 + P313 - P405 - P501
Personal Protective Equipment	Eyeshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 1
Flash Point(F)	392.0 °F - Pensky-Martens closed cup
Flash Point(C)	200 °C - Pensky-Martens closed cup

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Bismerthiazol

Empirical Formula (Hill Notation):	C₅H₆N₆S₄
CAS Number:	79319-85-0
Molecular Weight:	278.40
MDL number:	MFCD01681864
PubChem Substance ID:	329754920

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
mp	194-198 °C
suitability	complies for identity (by LC-MS)
Featured Industry	Agriculture Environmental
format	neat
SMILES string	S=C1NN=C(NCNC2=NNC(=S)S2)S1
InChI	1S/C5H6N6S4/c12-4-10-8-2(14-4)6-1-7-3-9-11-5(13)15-3/h1H2,(H,6,8)(H,7,9)(H,10,12)(H,11,13)
InChI key	RSNWORHVUOZYLT-UHFFFAOYSA-N

Bispyribac sodium belongs to the class of pyrimidinyl carboxy herbicides utilized for the post-emergence control of cyperaceous and dicotyledonous grasses and broad-leaf weeds.

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bispyribac sodium salt

Empirical Formula (Hill Notation):	C₁₉H₁₇N₄NaO₈
CAS Number:	125401-92-5
Molecular Weight:	452.35
MDL number:	MFCD02314071
PubChem Substance ID:	329754414
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Bispyribac sodium may be used as an analytical reference standard for the determination of the analyte in:

Water samples and agricultural products by liquid chromatography-tandem mass spectrometry (LC-MS/MS).
Fruits and vegetables by liquid chromatography–quadrupole-time of flight–mass spectrometry (LC-QTOF-MS) with automated detection.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	[Na+].COc1cc(OC)nc(Oc2cccc(Oc3nc(OC)cc(OC)n3)c2C([O-])=O)n1
InChI	1S/C19H18N4O8.Na/c1-26-12-8-13(27-2)21-18(20-12)30-10-6-5-7-11(16(10)17(24)25)31-19-22-14(28-3)9-15(23-19)29-4;/h5-9H,1-4H3,(H,24,25);/q;+1/p-1
InChI key	FUHMZYWBSHTEDZ-UHFFFAOYSA-M

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07
signalword	Warning
hcodes	H319
pcodes	P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Bistrifluron

Empirical Formula (Hill Notation):	C₁₆H₇ClF₈N₂O₂
CAS Number:	201593-84-2
Molecular Weight:	446.68
MDL number:	MFCD22581210
PubChem Substance ID:	329760077
NACRES:	NA.24

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
assay	98.0% (HPLC)
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	Fc1cccc(F)c1C(=O)NC(=O)Nc2cc(cc(c2Cl)C(F)(F)F)C(F)(F)F
InChI	1S/C16H7ClF8N2O2/c17-12-7(16(23,24)25)4-6(15(20,21)22)5-10(12)26-14(29)27-13(28)11-8(18)2-1-3-9(11)19/h1-5H,(H2,26,27,28,29)
InChI key	YNKFZRGTXAPYFD-UHFFFAOYSA-N