Supelco

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
assay	98.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
mp	70-75 °C
Featured Industry	Agriculture
format	neat
storage temp.	2-8°C
SMILES string	O=C1N(CSP(OC([2H])([2H])[2H])(OC([2H])([2H])[2H])=S)C(C2=CC=CC=C21)=O
InChI	1S/C11H12NO4PS2/c1-15-17(18,16-2)19-7-12-10(13)8-5-3-4-6-9(8)11(12)14/h3-6H,7H2,1-2H3/i1D3,2D3
InChI key	LMNZTLDVJIUSHT-WFGJKAKNSA-N

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H301 - H312 - H330 - H410
pcodes	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P310
RIDADR	UN 2811 6.1 / PGII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Picloram

Empirical Formula (Hill Notation):	C₆H₃Cl₃N₂O₂
CAS Number:	1918-02-1
Molecular Weight:	241.46
Beilstein/REAXYS Number:	479075
EC Number:	217-636-1
MDL number:	MFCD00012101
PubChem Substance ID:	329755506
NACRES:	NA.24

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
mp	200 °C (dec.) (lit.)
Featured Industry	Agriculture Environmental
format	neat
SMILES string	Nc1c(Cl)c(Cl)nc(C(O)=O)c1Cl
InChI	1S/C6H3Cl3N2O2/c7-1-3(10)2(8)5(9)11-4(1)6(12)13/h(H2,10,11)(H,12,13)
InChI key	NQQVFXUMIDALNH-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07
signalword	Warning
hcodes	H319
pcodes	P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Picolinafen

Empirical Formula (Hill Notation):	C₁₉H₁₂F₄N₂O₂
CAS Number:	137641-05-5
Molecular Weight:	376.30
MDL number:	MFCD04040061
PubChem Substance ID:	329755722
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	Fc1ccc(NC(=O)c2cccc(Oc3cccc(c3)C(F)(F)F)n2)cc1
InChI	1S/C19H12F4N2O2/c20-13-7-9-14(10-8-13)24-18(26)16-5-2-6-17(25-16)27-15-4-1-3-12(11-15)19(21,22)23/h1-11H,(H,24,26)
InChI key	CWKFPEBMTGKLKX-UHFFFAOYSA-N

Picoxystrobin is classified under the strobulins family of fungicides that exhibit broad range activity against plant pathogenspathogenic fungi.

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273 - P391 - P501
Personal Protective Equipment	Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Picoxystrobin

Empirical Formula (Hill Notation):	C₁₈H₁₆F₃NO₄
CAS Number:	117428-22-5
Molecular Weight:	367.32
MDL number:	MFCD04112618
PubChem Substance ID:	329754607
NACRES:	NA.24

Picoxystrobin may be used as a reference standard for the determination of picoxystrobin in:

Honeybees using acetonitrile-based extraction followed by dispersive solid-phase extraction (d-SPE) cleanup and gas chromatographytandem quadrupole mass spectrometry (GCMS/MS).
Foodstuffs by liquid chromatography (LC) combined with MS/MS, atmospheric pressure chemical ionization (APCI) and electrospray ionization (ESI).
Paddy field water by direct injection using LC coupled with quadrupole-linear ion trap (QqLIT)-MS.
Maize by acetonitrile-based extraction with dispersive liquidliquid microextraction (DLLME) followed by GC-MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CO\C=C(/C(=O)OC)c1ccccc1COc2cccc(n2)C(F)(F)F
InChI	1S/C18H16F3NO4/c1-24-11-14(17(23)25-2)13-7-4-3-6-12(13)10-26-16-9-5-8-15(22-16)18(19,20)21/h3-9,11H,10H2,1-2H3/b14-11-
InChI key	IBSNKSODLGJUMQ-KAMYIIQDSA-N

Pindone is a first generation anticoagulant rodenticide, belonging to the class of indandione rodenticide, commonly used for commensal rodent control.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H332 - H410
pcodes	P273 - P304 + P340 + P312
Personal Protective Equipment	Eyeshields, Faceshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pindone

Empirical Formula (Hill Notation):	C₁₄H₁₄O₃
CAS Number:	83-26-1
Molecular Weight:	230.26
Beilstein/REAXYS Number:	2051258
EC Number:	201-462-8
MDL number:	MFCD00021230
PubChem Substance ID:	329756840
NACRES:	NA.24

Pindone may be used as an analytical reference standard for the quantification of the analyte in biological samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC(C)(C)C(=O)C1C(=O)c2ccccc2C1=O
InChI	1S/C14H14O3/c1-14(2,3)13(17)10-11(15)8-6-4-5-7-9(8)12(10)16/h4-7,10H,1-3H3
InChI key	RZKYEQDPDZUERB-UHFFFAOYSA-N

Pinoxaden belongs to phenylpyrazolines class. It is a post-emergence, selective herbicide used widely for a variety of annual grass weeds.

pictograms	GHS06,GHS08,GHS09
signalword	Danger
hcodes	H301 - H372 - H410
pcodes	P273 - P301 + P310 + P330 - P314
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN2811 - class 6.1 - PG 3 - MP - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pinoxaden

Empirical Formula (Hill Notation):	C₂₃H₃₂N₂O₄
CAS Number:	243973-20-8
Molecular Weight:	400.51
MDL number:	MFCD08690563
PubChem Substance ID:	329754340
NACRES:	NA.24

Pinoxaden may be used as a reference standard for the determination of pinoxaden in food samples by ultrasonification assisted extraction and high performance liquid chromatography.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Caution

Product is moisture sensitive (decomposition)

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCc1cc(C)cc(CC)c1C2=C(OC(=O)C(C)(C)C)N3CCOCCN3C2=O
InChI	1S/C23H32N2O4/c1-7-16-13-15(3)14-17(8-2)18(16)19-20(26)24-9-11-28-12-10-25(24)21(19)29-22(27)23(4,5)6/h13-14H,7-12H2,1-6H3
InChI key	MGOHCFMYLBAPRN-UHFFFAOYSA-N

pictograms	GHS07,GHS08,GHS09
signalword	Warning
hcodes	H302 + H332 - H317 - H319 - H335 - H361d - H410
pcodes	P273 - P280 - P301 + P312 - P302 + P352 - P304 + P340 + P312 - P308 + P313
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pinoxaden Metabolite SYN502836 CRM80876-10MG

Empirical Formula (Hill Notation):	C₁₈H₂₂N₂O₅
CAS Number:	881376-42-7
Molecular Weight:	346.38

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.

TraceCERT is a registered trademark of Sigma-Aldrich Co. LLC

Quality Level	300
grade	certified reference material, TraceCERT^®
product line	TraceCERT^®
shelf life	limited shelf life, expiry date on the label
format	neat
storage temp.	2-8°C

pictograms	GHS07,GHS08,GHS09
signalword	Danger
hcodes	H302 + H332 - H319 - H334 - H335 - H361d - H410
pcodes	P201 - P273 - P301 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
Target Organs	Respiratory system
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pinoxaden Metabolite SYN505164 18029-10MG

Empirical Formula (Hill Notation):	C₁₈H₂₄N₂O₄
CAS Number:	881376-41-6
Molecular Weight:	332.39

This reference material (RM) is produced and certified in accordance with ISO/IEC 17025. This RM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content incl. uncertainty and expiry date are given on the certificate.

Quality Level	200
grade	reference material
assay	≥95.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
format	neat
storage temp.	−20°C
SMILES string	CCC1=C(C2C(N(CCOCC3)N3C2=O)=O)C(CC)=CC(CO)=C1

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H315 - H317 - H319 - H332 - H335 - H411
pcodes	P273 - P280 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338
Target Organs	Respiratory system
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Piperonylbutoxide

Empirical Formula (Hill Notation):	C₁₉H₃₀O₅
CAS Number:	51-03-6
Molecular Weight:	338.44
Beilstein/REAXYS Number:	288063
EC Number:	200-076-7
MDL number:	MFCD00005842
PubChem Substance ID:	329756841

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
refractive index	n20/D 1.498 (lit.)
bp	155 °C/0.3 mmHg (lit.)
density	1.059 g/mL at 25 °C (lit.)
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCCCOCCOCCOCc1cc2OCOc2cc1CCC
InChI	1S/C19H30O5/c1-3-5-7-20-8-9-21-10-11-22-14-17-13-19-18(23-15-24-19)12-16(17)6-4-2/h12-13H,3-11,14-15H2,1-2H3
InChI key	FIPWRIJSWJWJAI-UHFFFAOYSA-N

Piperophos belongs to the class of organophosphorus insecticides, commonly present as an endocrine disrupting chemical with anti-androgenic activity.

pictograms	GHS09
signalword	Warning
hcodes	H410
pcodes	P273 - P391 - P501
Personal Protective Equipment	Eyeshields, Gloves
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 3
Flash Point F	339.8 °F - closed cup
Flash Point C	171 °C - closed cup

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Piperonylbutoxide-(butyl-d9)

Empirical Formula (Hill Notation): C₁₉D₉H₂₁O₅

CAS Number: 1329834-53-8

Molecular Weight: 347.49

NACRES: NA.24

Кат. номер

73879-10MG

73879-VAR

General description
Piperonylbutoxide-(butyl-d9) is an isotope labeled analog of the insecticide synergist piperonyl butoxide, wherein the butoxy protons are replaced by deuterium.
Application
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis, potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.
Legal Information
PESTANAL is a registered trademark of Sigma-Aldrich International GmbH
Параметры

grade analytical standard

Quality Level 100

product line PESTANAL^®

assay 97.0% (HPLC)

shelf life limited shelf life, expiry date on the label

Featured Industry Agriculture
Environmental

format neat

Safety Information

pictograms GHS09

signalword Warning

hcodes H410

pcodes P273 - P391 - P501

RIDADR UN 3077 9 / PGIII

WGK Germany WGK 3

Flash Point F Not applicable

Flash Point C Not applicable

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Piperophos

Empirical Formula (Hill Notation):	C₁₄H₂₈NO₃PS₂
CAS Number:	24151-93-7
Molecular Weight:	353.48
Beilstein/REAXYS Number:	8395577
MDL number:	MFCD00210346
PubChem Substance ID:	329757052
NACRES:	NA.24

Piperophos may be used as an analytical reference standard for the quantification of the analyte in environmental samples, bovine milk samples and paprika using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCCOP(=S)(OCCC)SCC(=O)N1CCCCC1C
InChI	1S/C14H28NO3PS2/c1-4-10-17-19(20,18-11-5-2)21-12-14(16)15-9-7-6-8-13(15)3/h13H,4-12H2,1-3H3
InChI key	UNLYSVIDNRIVFJ-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H302 - H330 - H410
pcodes	P273 - P301 + P312 + P330 - P304 + P340 + P310
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 3
Flash Point F	212.0 °F
Flash Point C	> 100 °C

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Pirimicarb

Empirical Formula (Hill Notation):	C₁₁H₁₈N₄O₂
CAS Number:	23103-98-2
Molecular Weight:	238.29
Beilstein/REAXYS Number:	663442
EC Number:	245-430-1
MDL number:	MFCD00055520
PubChem Substance ID:	329756842
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CN(C)C(=O)Oc1nc(nc(C)c1C)N(C)C
InChI	1S/C11H18N4O2/c1-7-8(2)12-10(14(3)4)13-9(7)17-11(16)15(5)6/h1-6H3
InChI key	YFGYUFNIOHWBOB-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS08,GHS09
signalword	Danger
hcodes	H301 + H331 - H317 - H351 - H410
pcodes	P201 - P273 - P280 - P301 + P310 + P330 - P302 + P352 - P304 + P340 + P311
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN2811 - class 6.1 - PG 3 - MP - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pirimicarb-d6

Empirical Formula (Hill Notation):	C₁₁D₆H₁₂N₄O₂
CAS Number:	1015854-66-6
Molecular Weight:	244.32
MDL number:	MFCD08273890
PubChem Substance ID:	329754894
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
mass shift	M+6
SMILES string	[2H]C([2H])([2H])N(C(=O)Oc1nc(nc(C)c1C)N(C)C)C([2H])([2H])[2H]
InChI	1S/C11H18N4O2/c1-7-8(2)12-10(14(3)4)13-9(7)17-11(16)15(5)6/h1-6H3/i5D3,6D3
InChI key	YFGYUFNIOHWBOB-SCPKHUGHSA-N

Pirimiphos-ethyl belongs to the class of organophosphorus pesticides, with contact and respiratory action and is commonly employed for the protection of crops including vegetables, bananas, turf and mushrooms. Its mode of action involves the inhibition of acetylcholinesterase activity.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H301 - H410
pcodes	P273 - P301 + P310 + P330
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN2811 - class 6.1 - PG 3 - MP - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pirimiphos-ethyl

Empirical Formula (Hill Notation):	C₁₃H₂₄N₃O₃PS
CAS Number:	23505-41-1
Molecular Weight:	333.39
Beilstein/REAXYS Number:	7141373
EC Number:	245-704-0
MDL number:	MFCD00055295
PubChem Substance ID:	329756843
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Pirimiphos-ethyl may be used as an analytical reference standard for the quantification of the analyte in honey bees and biological samples using different chromatography techniques.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCOP(=S)(OCC)Oc1cc(C)nc(n1)N(CC)CC
InChI	1S/C13H24N3O3PS/c1-6-16(7-2)13-14-11(5)10-12(15-13)19-20(21,17-8-3)18-9-4/h10H,6-9H2,1-5H3
InChI key	TZBPRYIIJAJUOY-UHFFFAOYSA-N

Pirimiphos-methyl (PMM) is an organophosphorous pesticide.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H301 - H312 - H410
pcodes	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN2810 - class 6.1 - PG 3 - SMP - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pirimiphos-methyl

Empirical Formula (Hill Notation):	C₁₁H₂₀N₃O₃PS
CAS Number:	29232-93-7
Molecular Weight:	305.33
Beilstein/REAXYS Number:	755726
EC Number:	249-528-5
MDL number:	MFCD00055366
PubChem Substance ID:	329753990
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
PMM may have been used as reference standard for identification of possible intermediate products formed during photocatalytic degradation of PMM using different chromatographic methods, like GC, HPLC, GC-MS, TOC and LC-MS.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCN(CC)c1nc(C)cc(OP(=S)(OC)OC)n1
InChI	1S/C11H20N3O3PS/c1-6-14(7-2)11-12-9(3)8-10(13-11)17-18(19,15-4)16-5/h8H,6-7H2,1-5H3
InChI key	QHOQHJPRIBSPCY-UHFFFAOYSA-N

Pirimiphos-methyl-(O,O-dimethyl-d6) is a deuterated analog of pirimiphos-methyl, an organophosphorus insecticide, wherein the O-methyl protons are substituted by deuterium.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H410
pcodes	P273 - P301 + P312 + P330
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 3

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Pirimiphos-methyl-(O,O-dimethyl-d6)

Empirical Formula (Hill Notation):	C₁₁D₆H₁₄N₃O₃PS
Molecular Weight:	311.37
MDL number:	MFCD08273892
PubChem Substance ID:	329755023
NACRES:	NA.24

Pirimiphos-methyl-(O,O-dimethyl-d6) may be used as a deuterated internal standard to quantify pesticides in wheat flour and wastewater by ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) and HPLC-MS/MS, respectively.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
shelf life	limited shelf life, expiry date on the label
Featured Industry	Agriculture
format	neat
storage temp.	2-8°C
SMILES string	CC1=NC(N(CC)CC)=NC(OP(OC([2H])([2H])[2H])(OC([2H])([2H])[2H])=S)=C1
InChI	1S/C11H20N3O3PS/c1-6-14(7-2)11-12-9(3)8-10(13-11)17-18(19,15-4)16-5/h8H,6-7H2,1-5H3/i4D3,5D3
InChI key	QHOQHJPRIBSPCY-RKAHMFOGSA-N

Piroctone olamine is a pyridone derivative, which is known to have bactericidal effects on gram-positive and gram-negative bacteria and fungicidal effects and hence is a component of many cosmetic products such as anti-dandruff shampoo.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H410
pcodes	P273 - P301 + P312 + P330
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Piroctone olamine

Empirical Formula (Hill Notation):	C₁₄H₂₃NO₂ · C₂H₇NO
CAS Number:	68890-66-4
Molecular Weight:	298.42
EC Number:	272-574-2
MDL number:	MFCD01690792
PubChem Substance ID:	329757760
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
assay	99.0% (HPLC)
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	NCCO.CC(CC1=CC(C)=CC(=O)N1O)CC(C)(C)C
InChI	1S/C14H23NO2.C2H7NO/c1-10-6-12(15(17)13(16)8-10)7-11(2)9-14(3,4)5;3-1-2-4/h6,8,11,17H,7,9H2,1-5H3;4H,1-3H2
InChI key	BTSZTGGZJQFALU-UHFFFAOYSA-N

Prallethrins are classified under the broad category of pyrethroid insecticides that are utilized in agricultural, domestic and industrial applications. They are typically used for protection against mosquitoes, cockroaches as well as other insects.

pictograms	GHS05
signalword	Danger
hcodes	H315 - H318 - H412
pcodes	P273 - P280 - P302 + P352 - P305 + P351 + P338 + P310
Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	323.4 °F
Flash Point C	161.9 °C

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Prallethrin

Empirical Formula (Hill Notation):	C₁₉H₂₄O₃
CAS Number:	23031-36-9
Molecular Weight:	300.39
EC Number:	245-387-9
MDL number:	MFCD03792792
PubChem Substance ID:	329754385
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Prallethrin may be used as an analytical reference standard for the determination of the analyte in:

Sediment samples by dichloromethane (DMC)-based Soxhlet extraction and high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS).
Domestic wastewater samples by ultrasound-assisted dispersive liquid–liquid microextraction (UA-DLLME) combined with capillary GC.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	C\C(C)=C/C1C(C(=O)OC2CC(=O)C(CC#C)=C2C)C1(C)C
InChI	1S/C19H24O3/c1-7-8-13-12(4)16(10-15(13)20)22-18(21)17-14(9-11(2)3)19(17,5)6/h1,9,14,16-17H,8,10H2,2-6H3
InChI key	SMKRKQBMYOFFMU-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H302 - H331 - H410
pcodes	P261 - P264 - P270 - P273 - P301 + P312 - P304 + P340 + P311
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN2811 - class 6.1 - PG 1 - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point F	282.2 °F - closed cup
Flash Point C	139 °C - closed cup

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Pretilachlor

Empirical Formula (Hill Notation):	C₁₇H₂₆ClNO₂
CAS Number:	51218-49-6
Molecular Weight:	311.85
Beilstein/REAXYS Number:	2754162
MDL number:	MFCD00161476
PubChem Substance ID:	329753700
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCCOCCN(C(=O)CCl)c1c(CC)cccc1CC
InChI	1S/C17H26ClNO2/c1-4-11-21-12-10-19(16(20)13-18)17-14(5-2)8-7-9-15(17)6-3/h7-9H,4-6,10-13H2,1-3H3
InChI key	YLPGTOIOYRQOHV-UHFFFAOYSA-N

pictograms	GHS06
signalword	Danger
hcodes	H315 - H331
pcodes	P261 - P264 - P271 - P280 - P302 + P352 - P304 + P340 + P311
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Pretilachlor 38947-100MG

Empirical Formula (Hill Notation):	C₁₇H₂₆ClNO₂
CAS Number:	51218-49-6
Molecular Weight:	311.85
Beilstein/REAXYS Number:	2754162
MDL number:	MFCD00161476

Quality Level	200
grade	reference material
assay	≥97.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
format	neat
storage temp.	2-8°C
SMILES string	CCCOCCN(C(=O)CCl)c1c(CC)cccc1CC
InChI	1S/C17H26ClNO2/c1-4-11-21-12-10-19(16(20)13-18)17-14(5-2)8-7-9-15(17)6-3/h7-9H,4-6,10-13H2,1-3H3
InChI key	YLPGTOIOYRQOHV-UHFFFAOYSA-N

Primisulfuron-methyl belongs to the class of sulfonylurea herbicides.

pictograms	GHS06
signalword	Danger
hcodes	H315 - H331
pcodes	P261 - P264 - P271 - P280 - P302 + P352 - P304 + P340 + P311
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Primisulfuron-methyl

Empirical Formula (Hill Notation):	C₁₅H₁₂F₄N₄O₇S
CAS Number:	86209-51-0
Molecular Weight:	468.34
Beilstein/REAXYS Number:	6673850
MDL number:	MFCD00337169
PubChem Substance ID:	329754209
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Primisulfuron-methyl may be used as an analytical reference standard for the determination of the analyte in:

Surface and groundwater samples by solid-phase extraction (SPE) and high performance liquid chromatography-electrospray ionization-mass spectrometry (HPLC/ESI-MS).
Tap and leaching water samples by SPE and LC coupled to tandem mass spectrometry (MS/MS) with ESI and selected reaction monitoring (SRM) detection.
Wine samples by vortex-assisted ionic liquid dispersive liquid–liquid microextraction ((VA-IL-DLLME)) and capillary HPLC.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	COC(=O)c1ccccc1S(=O)(=O)NC(=O)Nc2nc(OC(F)F)cc(OC(F)F)n2
InChI	1S/C15H12F4N4O7S/c1-28-11(24)7-4-2-3-5-8(7)31(26,27)23-15(25)22-14-20-9(29-12(16)17)6-10(21-14)30-13(18)19/h2-6,12-13H,1H3,(H2,20,21,22,23,25)
InChI key	ZTYVMAQSHCZXLF-UHFFFAOYSA-N

Prochloraz belongs to the imidazole class of fungicides, with protective and curative action, found to be effective against different fungi affecting cereal crops, turf, citrus and tropical fruit, field legumes and beet. Its mode of action involves the inhibition of ergosterol biosynthesis.

pictograms	GHS09
signalword	Warning
hcodes	H400
pcodes	P273 - P391 - P501
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Prochloraz

Empirical Formula (Hill Notation):	C₁₅H₁₆Cl₃N₃O₂
CAS Number:	67747-09-5
Molecular Weight:	376.67
Beilstein/REAXYS Number:	8155344
EC Number:	266-994-5
MDL number:	MFCD00078735
PubChem Substance ID:	329756845
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Prochloraz may be used as an analytical reference standard for the quantification of the analyte in agricultural commodities using different chromatography techniques.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCCN(CCOc1c(Cl)cc(Cl)cc1Cl)C(=O)n2ccnc2
InChI	1S/C15H16Cl3N3O2/c1-2-4-20(15(22)21-5-3-19-10-21)6-7-23-14-12(17)8-11(16)9-13(14)18/h3,5,8-10H,2,4,6-7H2,1H3
InChI key	TVLSRXXIMLFWEO-UHFFFAOYSA-N

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H410
pcodes	P273 - P301 + P312 + P330
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Prochloraz Metabolite BTS40348

Empirical Formula (Hill Notation):	C₁₁H₁₄Cl₃NO
CAS Number:	67747-01-7
Molecular Weight:	282.59
Beilstein/REAXYS Number:	6401835
MDL number:	MFCD09751307
PubChem Substance ID:	329754990
NACRES:	NA.24

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
shelf life	limited shelf life, expiry date on the label
Featured Industry	Agriculture Environmental
format	neat
SMILES string	ClC1=C(OCCNCCC)C(Cl)=CC(Cl)=C1
InChI	1S/C11H14Cl3NO/c1-2-3-15-4-5-16-11-9(13)6-8(12)7-10(11)14/h6-7,15H,2-5H2,1H3
InChI key	CLFQSOIBYICELN-UHFFFAOYSA-N

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

pictograms	GHS07
signalword	Warning
hcodes	H302 - H413
pcodes	P301 + P312 + P330
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Prochloraz Metabolite BTS44595

Empirical Formula (Hill Notation):	C₁₂H₁₅Cl₃N₂O₂
CAS Number:	139520-94-8
Molecular Weight:	325.62
MDL number:	MFCD04125365
PubChem Substance ID:	329754989

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
shelf life	limited shelf life, expiry date on the label
Featured Industry	Agriculture Environmental
format	neat
SMILES string	ClC1=C(OCCN(C(N)=O)CCC)C(Cl)=CC(Cl)=C1
InChI	1S/C12H15Cl3N2O2/c1-2-3-17(12(16)18)4-5-19-11-9(14)6-8(13)7-10(11)15/h6-7H,2-5H2,1H3,(H2,16,18)
InChI key	MPNJTIZLDHWBFX-UHFFFAOYSA-N

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

pictograms	GHS07
signalword	Warning
hcodes	H302
pcodes	P301 + P312 + P330
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Prochloraz Metabolite BTS44596

Empirical Formula (Hill Notation):	C₁₃H₁₅Cl₃N₂O₃
CAS Number:	139542-32-8
Molecular Weight:	353.63
Beilstein/REAXYS Number:	9142204
MDL number:	MFCD28122615
PubChem Substance ID:	329755013
NACRES:	NA.24

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
shelf life	limited shelf life, expiry date on the label
format	neat
SMILES string	ClC1=C(OCCN(CCC)C(NC([H])=O)=O)C(Cl)=CC(Cl)=C1
InChI	1S/C13H15Cl3N2O3/c1-2-3-18(13(20)17-8-19)4-5-21-12-10(15)6-9(14)7-11(12)16/h6-8H,2-5H2,1H3,(H,17,19,20)
InChI key	RHDVQZWCBQXOJW-UHFFFAOYSA-N

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

pictograms	GHS07
signalword	Warning
hcodes	H302 - H315 - H319
pcodes	P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Prochloraz-(ethylene-d4)

Empirical Formula (Hill Notation):	C₁₅D₄H₁₂Cl₃N₃O₂
Molecular Weight:	380.69
NACRES:	NA.24

grade	analytical standard
Quality Level	100
isotopic purity	95.0 atom % D
product line	PESTANAL^®
assay	98.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
Featured Industry	Agriculture
format	neat
SMILES string	O=C(N1C=NC=C1)N(CCC)C([2H])([2H])C([2H])([2H])OC2=C(Cl)C=C(Cl)C=C2Cl

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H410
pcodes	P273 - P301 + P312 + P330 - P391 - P501
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3

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Procymidone

Empirical Formula (Hill Notation):	C₁₃H₁₁Cl₂NO₂
Molecular Weight:	284.14
Beilstein/REAXYS Number:	1539058
EC Number:	251-233-1
MDL number:	MFCD00078740
PubChem Substance ID:	329755429
NACRES:	NA.24

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC12CC1(C)C(=O)N(C2=O)c3cc(Cl)cc(Cl)c3
InChI	1S/C13H11Cl2NO2/c1-12-6-13(12,2)11(18)16(10(12)17)9-4-7(14)3-8(15)5-9/h3-5H,6H2,1-2H3
InChI key	QXJKBPAVAHBARF-UHFFFAOYSA-N

Profenofos is a broad-spectrum organophosphorus pesticide, commonly used for the control of various insect pests on vegetable crops.

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2

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Profenofos

Empirical Formula (Hill Notation):	C₁₁H₁₅BrClO₃PS
CAS Number:	41198-08-7
Molecular Weight:	373.63
Beilstein/REAXYS Number:	2150258
EC Number:	255-255-2
MDL number:	MFCD00078736
PubChem Substance ID:	329756846
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Profenofos may be used as an analytical reference standard for the quantification of the analyte in vegetables using high-performance liquid chromatography.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCCSP(=O)(OCC)Oc1ccc(Br)cc1Cl
InChI	1S/C11H15BrClO3PS/c1-3-7-18-17(14,15-4-2)16-11-6-5-9(12)8-10(11)13/h5-6,8H,3-4,7H2,1-2H3
InChI key	QYMMJNLHFKGANY-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 + H312 + H332 - H317 - H410
pcodes	P261 - P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	255.2 °F - closed cup
Flash Point C	124 °C - closed cup

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Profluralin

Empirical Formula (Hill Notation):	C₁₄H₁₆F₃N₃O₄
CAS Number:	26399-36-0
Molecular Weight:	347.29
Beilstein/REAXYS Number:	2179006
EC Number:	247-656-6
MDL number:	MFCD00055480
PubChem Substance ID:	329756847

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCCN(CC1CC1)c2c(cc(cc2[N+]([O-])=O)C(F)(F)F)[N+]([O-])=O
InChI	1S/C14H16F3N3O4/c1-2-5-18(8-9-3-4-9)13-11(19(21)22)6-10(14(15,16)17)7-12(13)20(23)24/h6-7,9H,2-5,8H2,1H3
InChI key	ITVQAKZNYJEWKS-UHFFFAOYSA-N

Profoxydim is a pesticide used for the control of crabgrass, yellow bristle grass and barnyard grass in seeded and transplanted rice.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H319 - H410
pcodes	P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Profoxydim lithium salt

Empirical Formula (Hill Notation):	C₂₄H₃₁ClLiNO₄S
CAS Number:	192326-75-3
Molecular Weight:	471.97
MDL number:	MFCD04112607
PubChem Substance ID:	329754633
NACRES:	NA.24

Profoxydim lithium salt may be used as an analytical reference standard for the determination of profoxydim in rice grain samples and rice paddy systems using matrix solid-phase dispersion (MSPD) extraction followed by high-performance liquid chromatography-diode array detection (HPLC-DAD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	[Li+].CCC\C(=N/OCC(C)Oc1ccc(Cl)cc1)C2=C([O-])CC(CC2=O)C3CCCSC3
InChI	1S/C24H32ClNO4S.Li/c1-3-5-21(26-29-14-16(2)30-20-9-7-19(25)8-10-20)24-22(27)12-18(13-23(24)28)17-6-4-11-31-15-17;/h7-10,16-18,27H,3-6,11-15H2,1-2H3;/q;+1/p-1/b26-21+;
InChI key	LRGTYGSKTGIXOL-HCPJHKKFSA-M

Prohexadione-Calcium (Pro-Ca, prohexadione-Ca or BX-112) is a plant growth retardant which is used to inhibit gibberellin biosynthesis of plants. It generally reduces shoot elongation in plants.

pictograms	GHS07,GHS08
signalword	Warning
hcodes	H317 - H351 - H361d
pcodes	P201 - P280 - P302 + P352 - P308 + P313
Personal Protective Equipment	Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Prohexadione-Calcium

Empirical Formula (Hill Notation):	C₁₀H₁₀CaO₅
CAS Number:	127277-53-6
Molecular Weight:	250.26
MDL number:	MFCD03095704
PubChem Substance ID:	329753902
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	[Ca++].CC\C([O-])=C1/C(=O)CC(CC1=O)C([O-])=O
InChI	1S/C10H12O5.Ca/c1-2-6(11)9-7(12)3-5(10(14)15)4-8(9)13;/h5,11H,2-4H2,1H3,(H,14,15);/q;+2/p-2/b9-6-;
InChI key	NLKUPINTOLSSLD-BORNJIKYSA-L

Promecarb is a broad spectrum pesticide containing the N-methylcarbamate group. Its mode of action involves inhibiting the cholinesterase enzyme activity.

Personal Protective Equipment	Eyeshields, Gloves, type N95 (US)
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Promecarb

Empirical Formula (Hill Notation):	C₁₂H₁₇NO₂
CAS Number:	2631-37-0
Molecular Weight:	207.27
Beilstein/REAXYS Number:	2111695
EC Number:	220-113-0
MDL number:	MFCD00078728
PubChem Substance ID:	329756848
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Promecarb may be used as a reference standard for the determination of promecarb in water by solid-phase extraction and liquid chromatography coupled with ionspray mass spectrometry.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CNC(=O)Oc1cc(C)cc(c1)C(C)C
InChI	1S/C12H17NO2/c1-8(2)10-5-9(3)6-11(7-10)15-12(14)13-4/h5-8H,1-4H3,(H,13,14)
InChI key	DTAPQAJKAFRNJB-UHFFFAOYSA-N

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H300 - H311 - H410
pcodes	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RIDADR	UN2811 - class 6.1 - PG 2 - MP - RQ - Toxic solids, organic, n.o.s. HI: all
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Promecarb 39331-50MG

Empirical Formula (Hill Notation):	C₁₂H₁₇NO₂
CAS Number:	2631-37-0
Molecular Weight:	207.27
Beilstein/REAXYS Number:	2111695
MDL number:	MFCD00078728

Quality Level	200
grade	reference material
assay	≥98.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
format	neat
SMILES string	CNC(=O)Oc1cc(C)cc(c1)C(C)C
InChI	1S/C12H17NO2/c1-8(2)10-5-9(3)6-11(7-10)15-12(14)13-4/h5-8H,1-4H3,(H,13,14)
InChI key	DTAPQAJKAFRNJB-UHFFFAOYSA-N

Prometryn belongs to the class of triazine herbicide compounds.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H300 - H311 - H410
pcodes	P264 - P270 - P273 - P280 - P301 + P310 - P302 + P352 + P312
WGK Germany	WGK 3

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Prometryn

Empirical Formula (Hill Notation):	C₁₀H₁₉N₅S
CAS Number:	7287-19-6
Molecular Weight:	241.36
Beilstein/REAXYS Number:	613575
EC Number:	230-711-3
MDL number:	MFCD00055396
PubChem Substance ID:	329756850
NACRES:	NA.24

Prometryn may be used as an analytical reference standard for the identification of prometryn in:

Fruits and vegetable samples by citrate QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction and gas chromatography coupled to high resolution accurate mass spectrometry (GC-HRAMS) with electrospray ionization (ESI).
Seawater samples by solid-phase extraction (SPE) and ultra-pressure liquid chromatography coupled to tandem mass spectrometry (UPLC-MS/MS) equipped with ESI and multiple reaction monitoring (MRM) detection.
Sediment samples by dispersive-SPE, QuEChERS extraction and UPLC coupled to high resolution linear ion trap/Orbitrap (LTQ Orbitrap) MS.
Cereals by QuEChERS extraction and GC-MS/MS equipped with MRM detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CSc1nc(NC(C)C)nc(NC(C)C)n1
InChI	1S/C10H19N5S/c1-6(2)11-8-13-9(12-7(3)4)15-10(14-8)16-5/h6-7H,1-5H3,(H2,11,12,13,14,15)
InChI key	AAEVYOVXGOFMJO-UHFFFAOYSA-N

Propachlor is a herbicide, widely used in oil seeds and crop planting.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 + H332 - H410
pcodes	P261 - P264 - P270 - P273 - P301 + P312 - P304 + P340 + P312
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 2

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Propachlor

Empirical Formula (Hill Notation):	C₁₁H₁₄ClNO
CAS Number:	1918-16-7
Molecular Weight:	211.69
Beilstein/REAXYS Number:	2103903
EC Number:	217-638-2
MDL number:	MFCD00078731
PubChem Substance ID:	329756851
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Propachlor may be used as an analytical reference standard for the quantification of the analyte in industrial wastewater samples and complex matrices using chromatography techniques.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC(C)N(C(=O)CCl)c1ccccc1
InChI	1S/C11H14ClNO/c1-9(2)13(11(14)8-12)10-6-4-3-5-7-10/h3-7,9H,8H2,1-2H3
InChI key	MFOUDYKPLGXPGO-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H302 - H311 - H317 - H319 - H410
pcodes	P261 - P273 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	UN2811 - class 6.1 - PG 3 - MP - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany	WGK 3

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Propachlor ESA sodium salt

Empirical Formula (Hill Notation):	C₁₁H₁₄NNaO₄S
CAS Number:	947601-88-9
Molecular Weight:	279.29
MDL number:	MFCD08702646
PubChem Substance ID:	329754852
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
Agency/Method	EPA 535
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	[Na+].CC(C)N(C(=O)CS([O-])(=O)=O)c1ccccc1
InChI	1S/C11H15NO4S.Na/c1-9(2)12(10-6-4-3-5-7-10)11(13)8-17(14,15)16;/h3-7,9H,8H2,1-2H3,(H,14,15,16);/q;+1/p-1
InChI key	BQFQHQFNSWKXJL-UHFFFAOYSA-M

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07
signalword	Warning
hcodes	H315 - H319 - H335
pcodes	P302 + P352 - P305 + P351 + P338
Target Organs	Respiratory system
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propachlor OA

Empirical Formula (Hill Notation):	C₁₁H₁₃NO₃
CAS Number:	70628-36-3
Molecular Weight:	207.23
Beilstein/REAXYS Number:	8762695
MDL number:	MFCD08702645
PubChem Substance ID:	329754851
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
Agency/Method	EPA 535
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC(C)N(c1ccccc1)C(=O)C(O)=O
InChI	1S/C11H13NO3/c1-8(2)12(10(13)11(14)15)9-6-4-3-5-7-9/h3-8H,1-2H3,(H,14,15)
InChI key	HYHJOUPYTUBFIX-UHFFFAOYSA-N

Propamocarb is a systemic fungicide, widely used for greenhouse vegetables and agricultural commodities, which shows protective action against phycomycetous diseases (Phythium, Phytophthora spp.).

pictograms	GHS07
signalword	Warning
hcodes	H317
pcodes	P280
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propamocarb

Empirical Formula (Hill Notation):	C₉H₂₀N₂O₂
CAS Number:	24579-73-5
Molecular Weight:	188.27
Beilstein/REAXYS Number:	2080745
MDL number:	MFCD00078717
PubChem Substance ID:	329756852
NACRES:	NA.24

Propamocarb may be used as an analytical reference standard for the quantification of the analyte in vegetables and fruits samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCCOC(=O)NCCCN(C)C
InChI	1S/C9H20N2O2/c1-4-8-13-9(12)10-6-5-7-11(2)3/h4-8H2,1-3H3,(H,10,12)
InChI key	WZZLDXDUQPOXNW-UHFFFAOYSA-N

Propamocarb-(propyl-d7) is an isotope-labeled analog of systemic fungicide propamocarb, wherein propyl protons are substituted by deuterium.

pictograms	GHS07
signalword	Warning
hcodes	H302
pcodes	P301 + P312 + P330
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	212.0 °F
Flash Point C	> 100 °C

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Propamocarb-(propyl-d7)

Empirical Formula (Hill Notation):	C₉D₇H₁₃N₂O₂
Molecular Weight:	195.31
MDL number:	MFCD04972577
PubChem Substance ID:	329768743
NACRES:	NA.24

Propamocarb-(propyl-d7) may be used as a deuterated internal standard to quantify the pesticide analytes in foods of plant origin by two-dimensional liquid chromatography-tandem mass spectrometry (LC-MS/MS).
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
assay	98.0% (GC)
shelf life	limited shelf life, expiry date on the label
Featured Industry	Agriculture
format	neat
storage temp.	2-8°C
SMILES string	CN(C)CCCNC(OC([2H])([2H])C([2H])([2H])C([2H])([2H])[2H])=O
InChI	1S/C9H20N2O2/c1-4-8-13-9(12)10-6-5-7-11(2)3/h4-8H2,1-3H3,(H,10,12)/i1D3,4D2,8D2
InChI key	WZZLDXDUQPOXNW-GZAMCDGTSA-N

Propanil is a contact, post-emergence herbicide, used in the cultivation of irrigated rice. Its mode of action involves controlling, the electron transport inhibition of photosynthesis in herbs of wide leaves.

pictograms	GHS07
signalword	Warning
hcodes	H302
pcodes	P301 + P312 + P330
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propanil

Empirical Formula (Hill Notation):	C₉H₉Cl₂NO
CAS Number:	709-98-8
Molecular Weight:	218.08
Beilstein/REAXYS Number:	2365645
EC Number:	211-914-6
MDL number:	MFCD00018149
PubChem Substance ID:	329756853
NACRES:	NA.24

Propanil may be used as an analytical reference standard for the quantification of the analyte in environmental samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CCC(=O)Nc1ccc(Cl)c(Cl)c1
InChI	1S/C9H9Cl2NO/c1-2-9(13)12-6-3-4-7(10)8(11)5-6/h3-5H,2H2,1H3,(H,12,13)
InChI key	LFULEKSKNZEWOE-UHFFFAOYSA-N

Propaquizafop is an aryloxyphenoxypropionate herbicide primarily used for post emergence control of weeds in agricultural products. Its mode of action involves inhibition of the plastid acetyl coenzyme A carboxylase (ACCase), a key enzyme in fatty acid biosynthesis.

pictograms	GHS07,GHS09
signalword	Warning
hcodes	H302 - H400
pcodes	P273 - P301 + P312 + P330
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propaquizafop

Empirical Formula (Hill Notation):	C₂₂H₂₂ClN₃O₅
CAS Number:	111479-05-1
Molecular Weight:	443.88
MDL number:	MFCD02181171
PubChem Substance ID:	329753825
NACRES:	NA.24

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Propaquizafop may be used as a reference standard for the determination of the pesticide:

In honeybee samples by liquid and gas chromatography coupled with tandem mass spectrometry with multiple-reaction monitoring.
In groundwater and surface water samples by direct injection-liquid chromatography–electrospray ionization-tandem mass spectrometry with multiple-reaction monitoring.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	C[C@@H](Oc1ccc(Oc2cnc3cc(Cl)ccc3n2)cc1)C(=O)OCCO\N=C(\C)C
InChI	1S/C22H22ClN3O5/c1-14(2)26-29-11-10-28-22(27)15(3)30-17-5-7-18(8-6-17)31-21-13-24-20-12-16(23)4-9-19(20)25-21/h4-9,12-13,15H,10-11H2,1-3H3/t15-/m1/s1
InChI key	FROBCXTULYFHEJ-OAHLLOKOSA-N

pictograms	GHS07
signalword	Warning
hcodes	H332
pcodes	P304 + P340 + P312
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propaquizafop 39464-50MG

Empirical Formula (Hill Notation):	C₂₂H₂₂ClN₃O₅
CAS Number:	111479-05-1
Molecular Weight:	443.88
MDL number:	MFCD02181171

grade	reference material
assay	≥97.0% (HPLC)
optical activity	[α]/D 27.0±3.0°, c = 0.5 in chloroform
shelf life	limited shelf life, expiry date on the label
format	neat
storage temp.	2-8°C
SMILES string	C[C@@H](Oc1ccc(Oc2cnc3cc(Cl)ccc3n2)cc1)C(=O)OCCO\N=C(\C)C
InChI	1S/C22H22ClN3O5/c1-14(2)26-29-11-10-28-22(27)15(3)30-17-5-7-18(8-6-17)31-21-13-24-20-12-16(23)4-9-19(20)25-21/h4-9,12-13,15H,10-11H2,1-3H3/t15-/m1/s1
InChI key	FROBCXTULYFHEJ-OAHLLOKOSA-N

pictograms	GHS07
signalword	Warning
hcodes	H332
pcodes	P261 - P271 - P304 + P340 + P312
WGK Germany	WGK 2
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propargite 40596-100MG

Empirical Formula (Hill Notation):	C₁₉H₂₆O₄S
CAS Number:	2312-35-8
Molecular Weight:	350.47
Beilstein/REAXYS Number:	6934289
MDL number:	MFCD00072448

grade	reference material
assay	≥97.0% (HPLC)
shelf life	limited shelf life, expiry date on the label
format	neat
storage temp.	−20°C
SMILES string	CC(C)(C)c1ccc(OC2CCCCC2OS(=O)OCC#C)cc1
InChI	1S/C19H26O4S/c1-5-14-21-24(20)23-18-9-7-6-8-17(18)22-16-12-10-15(11-13-16)19(2,3)4/h1,10-13,17-18H,6-9,14H2,2-4H3
InChI key	ZYHMJXZULPZUED-UHFFFAOYSA-N

Propetamphos is an organophosphate insecticide, which acts by inhibiting acetylcholinesterase (AChE) enzyme activity.

pictograms	GHS05,GHS06,GHS08,GHS09
signalword	Danger
hcodes	H315 - H318 - H330 - H351 - H410
pcodes	P201 - P273 - P280 - P302 + P352 - P304 + P340 + P310 - P305 + P351 + P338 + P310
WGK Germany	WGK 3
Flash Point F	160.5 °F - Pensky-Martens closed cup
Flash Point C	71.4 °C - Pensky-Martens closed cup

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Propetamphos

Empirical Formula (Hill Notation):	C₁₀H₂₀NO₄PS
CAS Number:	31218-83-4
Molecular Weight:	281.31
Beilstein/REAXYS Number:	1979853
EC Number:	250-517-2
MDL number:	MFCD00137384
PubChem Substance ID:	329754967
NACRES:	NA.24

Propetamphos may be used as an analytical reference standard for the determination of the analyte in human tissues, fruits and crops by various chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCNP(=S)(OC)O\C(C)=C\C(=O)OC(C)C
InChI	1S/C10H20NO4PS/c1-6-11-16(17,13-5)15-9(4)7-10(12)14-8(2)3/h7-8H,6H2,1-5H3,(H,11,17)/b9-7+
InChI key	BZNDWPRGXNILMS-VQHVLOKHSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS06,GHS09
signalword	Danger
hcodes	H301 + H311 - H330 - H410
pcodes	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P310
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN 3278 6.1 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propham

Empirical Formula (Hill Notation):	C₁₀H₁₃NO₂
CAS Number:	122-42-9
Molecular Weight:	179.22
Beilstein/REAXYS Number:	2209666
EC Number:	204-542-0
MDL number:	MFCD00026382
PubChem Substance ID:	329756855
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

grade	analytical standard
Quality Level	100
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
SMILES string	CC(C)OC(=O)Nc1ccccc1
InChI	1S/C10H13NO2/c1-8(2)13-10(12)11-9-6-4-3-5-7-9/h3-8H,1-2H3,(H,11,12)
InChI key	VXPLXMJHHKHSOA-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07
signalword	Warning
hcodes	H302
pcodes	P301 + P312 + P330
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propham solution

CAS Number:	122-42-9
Beilstein/REAXYS Number:	2209666
EC Number:	200-659-6
MDL number:	MFCD00026382
PubChem Substance ID:	329757007
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
shelf life	limited shelf life, expiry date on the label
concentration	100 µg/mL in methanol
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture
format	single component solution
storage temp.	2-8°C
SMILES string	CC(C)OC(=O)Nc1ccccc1
InChI	1S/C10H13NO2/c1-8(2)13-10(12)11-9-6-4-3-5-7-9/h3-8H,1-2H3,(H,11,12)
InChI key	VXPLXMJHHKHSOA-UHFFFAOYSA-N

Propiconazole is a systemic fungicide and its mode of action involves the inhibition of ergosterol biosynthesis.

pictograms	GHS02,GHS06,GHS08
signalword	Danger
hcodes	H225 - H301 + H311 + H331 - H370
pcodes	P210 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P311
Target Organs	Eyes
RIDADR	UN1230 - class 3 - PG 2 - Methanol
WGK Germany	WGK 1

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Propiconazole

Empirical Formula (Hill Notation):	C₁₅H₁₇Cl₂N₃O₂
CAS Number:	60207-90-1
Molecular Weight:	342.22
Beilstein/REAXYS Number:	9349305
EC Number:	262-104-4
MDL number:	MFCD00055299
PubChem Substance ID:	329756856
NACRES:	NA.24

Propiconazole may be used as an analytical reference standard for the quantification of the analyte in must, wine samples and environmental samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
description	mixture of stereo isomers
product line	PESTANAL^®
form	neat
shelf life	limited shelf life, expiry date on the label
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	neat
storage temp.	2-8°C
SMILES string	CCCC1COC(Cn2cncn2)(O1)c3ccc(Cl)cc3Cl
InChI	1S/C15H17Cl2N3O2/c1-2-3-12-7-21-15(22-12,8-20-10-18-9-19-20)13-5-4-11(16)6-14(13)17/h4-6,9-10,12H,2-3,7-8H2,1H3
InChI key	STJLVHWMYQXCPB-UHFFFAOYSA-N

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms	GHS07,GHS08,GHS09
signalword	Danger
hcodes	H302 - H317 - H360D - H410
pcodes	P202 - P273 - P280 - P301 + P312 - P302 + P352 - P308 + P313
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
RIDADR	UN 3082 9 / PGIII
WGK Germany	WGK 3
Flash Point F	Not applicable
Flash Point C	Not applicable

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Propiconazole solution

Empirical Formula (Hill Notation):	C₁₅H₁₇Cl₂N₃O₂
CAS Number:	60207-90-1
Molecular Weight:	342.22
Beilstein/REAXYS Number:	9349305
EC Number:	200-659-6
MDL number:	MFCD00055299
PubChem Substance ID:	329757008
NACRES:	NA.24

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Quality Level	100
grade	analytical standard
product line	PESTANAL^®
shelf life	limited shelf life, expiry date on the label
concentration	100 ng/µL in methanol
application(s)	HPLC: suitable, gas chromatography (GC): suitable
Featured Industry	Agriculture Environmental
format	single component solution
storage temp.	2-8°C
SMILES string	CCCC1COC(Cn2cncn2)(O1)c3ccc(Cl)cc3Cl
InChI	1S/C15H17Cl2N3O2/c1-2-3-12-7-21-15(22-12,8-20-10-18-9-19-20)13-5-4-11(16)6-14(13)17/h4-6,9-10,12H,2-3,7-8H2,1H3
InChI key	STJLVHWMYQXCPB-UHFFFAOYSA-N